Crystalline morphology of polymer

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August undefined, 2024

WebRecent observations on polymer single crystals are quoted in some detail. It is shown that these observations establish a hitherto unsuspected link between crystals of polymeric and simple substances, while on the other hand, they necessite the introduction of a new concept, the concept of chain-folding. WebSep 7, 2024 · Polymer Chemistry: Morphology. Polymer morphology is the overall form of polymer structure, including crystallinity, branching, molecular weight, cross-linking, and so on. Small molecules usually have crystalline solids, which are highly-ordered 3 … Polymer chemists sometimes refer to the threshold molecular weight below which … Thermosets usually are three-dimensional networked polymers in which there is a … In this case the solid is more irregular with polymer chains meandering in and out … Relatively short polymer chains form crystals more readily than long chains, …

Amorphous vs. Crystalline Polymers

WebThe initial crystalline morphology has been found to exert influence on the structural evolution of the samples, including cavitation, orientation behavior of molecular chains in crystalline and amorphous phases, the occurrence of mesophase, and reduction in crystallinity, etc. Compared with the iPPBu with spherulitic morphology, no obvious ... WebMay 19, 2024 · During the crystallization of polymers in confined systems, spherulitic and crystalline morphology can be investigated via polarized optical microscopy (POM), atomic force microscopy (AFM) and … north lake tahoe lodge

Deformation mechanisms in crystalline polymers SpringerLink

WebBassett DC (2005) The morphology of crystalline polymers. In: Michler GH, Baltá Calleja FJ (eds) Mechanical properties of polymers based on nanostructure and morphology. CRC Press (Taylor and Francis), Boca Raton, FL, Chap 1, p 3. Google Scholar Bassett DC (1981) Principles of polymer morphology. WebTitle: The morphology of crystalline polymers Author: P. H. Geil Subject: Journal of Chemical Education, Vol. 58 No.11, November 1981 p879, Keywords WebThe formation of nanoparticles and the mechanism of their formation in a blend of a thermotropic liquid crystalline polyester (LCP) and the zinc salt of a lightly sulfonated polystyrene ionomer (Zn-SPS) were investigated using Fourier transform infrared (FTIR), thermogravimetric analysis (TGA), and gas chromatography–mass spectroscopy … north lake tahoe lakefront homes for sale

Polymer Morphology - University of Cincinnati

Preparation and morphology control of porous microspheres of …

WebThrough control of the crystallization process many polymers can be made to exhibit a broad spectrum of structural possibilities, ranging from a state of high disorder to one of high order. Emphasis has been placed on bulk-crystallized polymers which normally fall near the center of this spectrum. WebDec 10, 2016 · Another approach to speed up the crystallization of semi-crystalline polymers is by using shear flow which can make polymer chains orientate along the flow direction, ... New understanding in tuning toughness of β-polypropylene: The role of β-nucleated crystalline morphology. Macromolecules 2009, 42, 9325–9331. [Google … how to say my bf in spanishWebThe rapidity of crystal growth from undercooled polymer melts precludes transformation of the randomly coiled macromolecules to the regularly folded morphology generally … north lake tahoe hotels tripadvisor

"WebOct 31, 2024 · This allows for discriminating between the different crystalline phases and defining the final morphology, which depends on which polymer block crystallizes first on the substrate. This work also shows that the use of epitaxial crystallization and the choice of suitable substrate offer a means to produce oriented nanostructures and morphologies ... " - Crystalline morphology of polymer

Crystalline morphology of polymer

Polymer Chemistry: Morphology - Engineering LibreTexts

WebIn addition to the development of phase morphology, crystalline morphology was investigated. The MFCs without an amorphous phase were analysed via SEM under high magnification. The spherulite structure developed in most of the samples, and a random orientation of the lamellae was noted in bulk polymer, as well as some spherulite … WebApr 8, 2008 · Crystalline morphology of electrospun polymeric nanofibers strongly influences the mechanical properties. In this study, electrospun polycaprolactone nanofibers with smaller diameters that are produced …

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WebAbstract IN a previous communication 1, it has been reported that when polyethylene terephthalate crystallizes, it forms spherulites, which consist of radiating helically … WebPolymer Morphology. Polymer morphology: Polymers may consist of both crystalline and amorphous regions, and polymer morphology describes the arrangement and …

WebCrystalline morphology of the matrix of PEEK-carbon fiber aromatic polymer composites. II. Crystallization behavior (Journal Article) OSTI.GOV skip to main content Sign In Create Account Show searchShow menu U.S. Department of EnergyOffice of Scientific and Technical Information Search terms:Advanced search options WebDec 21, 2024 · Crystalline polymers have a fully or partially regular chain structure, and in the regular parts they are able to crystallize to some extent.The crystalline stems adapt to a specific preferred conformation (cf. Chap. 2).The presence of chain defects, e.g. atactic sequences, chain branches or different repeating units at high concentrations, makes it …

WebMar 30, 2001 · Transesterification of polymer blends containing polyesters is often utilized to improve the interfacial adhesion and mechanical properties of a phase-separated blend. However, in some circumstances, the transesterification can also modify the morphology (crystallinity or liquid crystallinity) of the blend components due to the disruption of ... WebApr 12, 2024 · This work aimed to study the thermal and crystalline properties of poly (1,4-phenylene sulfide)@carbon char nanocomposites. Coagulation-processed nanocomposites of polyphenylene sulfide were prepared using the synthesized mesoporous nanocarbon of coconut shells as reinforcement. The mesoporous reinforcement was synthesized using …

WebApr 12, 2024 · This work aimed to study the thermal and crystalline properties of poly (1,4-phenylene sulfide)@carbon char nanocomposites. Coagulation-processed …

WebFeb 5, 2014 · Crystalline polymers form complex spherulitic morphologies upon crystallization from the melt. The spherulites are made of thin lamellae, frequently twisted, in which the long chains span the lamellar thickness and are folded back and forth at the lamellar surface. north lake tahoe hotels and resortsWebMar 12, 2003 · The morphology of crystalline polymers Authors: Abstract This article is a short reveiw of the development of our knowledge on the texture of crystalline … north lake tahoe hotelWebWith a focus on structure-property relationships, this book describes how polymer morphology affects properties and how scientists can modify them. The book covers structure development, theory, simulation, and … how to say my balls in spanishWebApr 12, 2024 · Since crystalline structures are linked to the presence of an interphase, the conditions for the crystallization process greatly influence the formation of the interphase region. ... The resulting cooling conditions alter the crystallization process and thus the morphology of the polymer matrix linked to the mechanical composite properties . north lake tahoe hotelsWebStated simply, polymer morphologies are either amorphous or crystalline. Amorphous molecules are arranged randomly and are intertwined, whereas crystalline molecules are arranged closely and in a discernible order. Most thermosets are amorphous, while thermoplastics may be amorphous or semicrystalline. how to say my baby in navajoWebPolymer Morphology will explore the details of structures commonly encountered in polymeric materials. The course will cover both well understood morphologies as well as … how to say my birthday is in frenchWebSep 20, 2024 · Crystallization of polymers Another factor that determines a polymer’s physical properties is its morphology, that is the alignment of the polymer chains. These chains fold together, and form ordered regions … how to say my beloved in spanish